
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia
Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina
Fil: Newman, Christoper P.. Quest International; Reino Unido
Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido
Fil: Sievert, Robert L.. Uniqema; Reino Unido
Models, Molecular, Green Chemistry, Formates, Carbohydrates, Carbonates, Molecular Conformation, Temperature, Green Chemistry Technology, Hydrogen-Ion Concentration, Methylation, carbohydrates; carbonates; green chemistry; methylation; renewable resources, Renewable Resources, https://purl.org/becyt/ford/1.4, Solvents, Indicators and Reagents, Isosorbide, https://purl.org/becyt/ford/1
Models, Molecular, Green Chemistry, Formates, Carbohydrates, Carbonates, Molecular Conformation, Temperature, Green Chemistry Technology, Hydrogen-Ion Concentration, Methylation, carbohydrates; carbonates; green chemistry; methylation; renewable resources, Renewable Resources, https://purl.org/becyt/ford/1.4, Solvents, Indicators and Reagents, Isosorbide, https://purl.org/becyt/ford/1
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