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Green Synthesis of Dimethyl Isosorbide

Authors: TUNDO, Pietro; ARICO', Fabio; G. Gauthier; L. Rossi; A. .E. Rosamilia; H. .S. Bevinakatti; R. .L. Sievert; +1 Authors

Green Synthesis of Dimethyl Isosorbide

Abstract

A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.

Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina

Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia

Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia

Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia

Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina

Fil: Newman, Christoper P.. Quest International; Reino Unido

Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido

Fil: Sievert, Robert L.. Uniqema; Reino Unido

Countries
Argentina, Italy
Keywords

Models, Molecular, Green Chemistry, Formates, Carbohydrates, Carbonates, Molecular Conformation, Temperature, Green Chemistry Technology, Hydrogen-Ion Concentration, Methylation, carbohydrates; carbonates; green chemistry; methylation; renewable resources, Renewable Resources, https://purl.org/becyt/ford/1.4, Solvents, Indicators and Reagents, Isosorbide, https://purl.org/becyt/ford/1

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    116
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
116
Top 1%
Top 10%
Top 10%
Green
bronze