Vibronic Transitions in Single Metalloporphyrins

descriptionPublicationkeyboard_double_arrow_right Article 22 Apr 2005 English Publisher:WileyJournal:ChemPhysChem, volume 6, pages 971-975 (issn: 1439-4235, eissn: 1439-7641,

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Authors: H J, Lee; J H, Lee; W, Ho;

doi: 10.1002/cphc.200400616

pmid: 15884084

Vibronic Transitions in Single Metalloporphyrins

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Abstract

AbstractStructural and electronic properties of single zinc etioporphyrin molecules adsorbed on Al2O3/NiAl(110) were probed by a low‐temperature scanning tunneling microscope (STM). Scanning tunneling spectroscopy (STS) revealed progressions of spectral features corresponding to the vibronic states of individual molecules that depend strongly on the molecular conformations. Vibronic features observed by STS were compared with the results from fluorescence induced by tunneling electrons (tunneling‐induced fluorescence, TIF).

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