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ChemInform Abstract: Cyclopropenes for the Synthesis of Cyclopropane‐Fused Dihydroquinolines and Benzazepines.

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 10 Sep 2015 English Publisher:WileyJournal:ChemInform, volume 47 (issn: 0931-7597, eissn: 1522-2667,

Authors: Hui-Xin Luo; Hui-Xin Luo; Xiao-Ping Cao; Xin-Shan Ye; Youhong Niu;

doi: 10.1002/chin.201605192 , 10.1002/adsc.201500203

ChemInform Abstract: Cyclopropenes for the Synthesis of Cyclopropane‐Fused Dihydroquinolines and Benzazepines.

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Abstract

AbstractA novel Povarov‐type three‐component reaction of cyclopropenes, anilines, and aromatic aldehydes is efficiently catalyzed by TfOH leading to desired cyclopropane‐fused dihydroquinolines (IV) and (VIII), which are converted into N‐triflated benzazepines (VI) and (IX), resp., via a ring opening/isomerization reaction.

Related Organizations

Peking University
China (People's Republic of)
Lanzhou University
China (People's Republic of)
State Key Laboratory of Natural and Biomimetic Drugs
China (People's Republic of)
Peking University
China (People's Republic of)

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