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ChemInform Abstract: Temperature Dependence of the Homolytic Abstraction of Benzylic Hydrogen by Bromine Atom

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Apr 1986Publisher:WileyJournal:Chemischer Informationsdienst, volume 17 (issn: 0009-2975, eissn: 2199-2924,

Authors: J. G. Wright; Richard D. Gilliom;

doi: 10.1002/chin.198634138 , 10.1021/ja00269a033

pmid: 22175580

ChemInform Abstract: Temperature Dependence of the Homolytic Abstraction of Benzylic Hydrogen by Bromine Atom

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Abstract

L'enlevement de l'hydrogene benzylique par l'atome de brome a partir du toluene et chloro-4 toluene a ete etudie en mesurant les vitesses relatives a 45°, 25°, 10°, 0°, −18,5°, −32° et −50°C. Les vitesses des chloro-3, bromo-4-, methyl-4- et nitro-4 toluenes par rapport au toluene sont determinees a −50°C

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