How Ionization Catalyzes Diels–Alder Reactions
Copyright policy )How Ionization Catalyzes Diels–Alder Reactions
AbstractInvited for the cover of this issue are Pascal Vermeeren, Trevor A. Hamlin, and F. Matthias Bickelhaupt of the TheoCheM group at the Vrije Universiteit Amsterdam. The cover art depicts how ionizing the dienophile lowers the Diels–Alder reaction barrier between 1,3‐butadiene and acrylaldehyde by reducing the destabilizing steric Pauli repulsion and enhancing the stabilizing orbital interactions. Read the full text of the article at 10.1002/chem.202200987.
- Radboud University Nijmegen Netherlands
- Vrije Universiteit Amsterdam Netherlands
reactivity, activation strain model, Chemical Phenomena, Cycloaddition Reaction, density functional calculations, Electrons, radical chemistry, Acrolein, Theoretical Chemistry, Diels-Alder reaction, SDG 6 - Clean Water and Sanitation, Research Articles, Catalysis
reactivity, activation strain model, Chemical Phenomena, Cycloaddition Reaction, density functional calculations, Electrons, radical chemistry, Acrolein, Theoretical Chemistry, Diels-Alder reaction, SDG 6 - Clean Water and Sanitation, Research Articles, Catalysis
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