Triple‐Bond Covalent Radii

descriptionPublicationkeyboard_double_arrow_right Article 30 May 2005 Germany English Publisher:WileyJournal:Chemistry – A European Journal, volume 11, pages 3,511-3,520 (issn: 0947-6539, eissn: 1521-3765,

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Authors: Pyykkö, Pekka; Hasenstab-Riedel, Sebastian; Patzschke, Michael;

doi: 10.1002/chem.200401299

pmid: 15832398

Triple‐Bond Covalent Radii

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Abstract

AbstractA system of additive covalent radii is proposed for σ2 π4 triple bonds involving elements from Be to E 112 (eka‐mercury). Borderline cases with weak multiple bonding are included. Only the elements in Group 1, the elements Zn–Hg in Group 12 and Ne in Group 18 are then totally excluded. Gaps are left at late actinides and some lanthanides. The standard deviation for the 324 included data points is 3.2 pm.

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Germany

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Keywords

Metals, Quantum Theory, Mathematics

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