Zur Konstitution des Xanthohumols
Copyright policy ) Herbert Hübner; Wolfgang Riedl;
Zur Konstitution des Xanthohumols
AbstractEs wird gezeigt, daß der aus Xanthohumol durch Alkali‐Abbau entstehende 2‐[γ.γ‐Dimethyl‐allyl]‐phloroglucin‐x‐methyläther mit dem 1‐Methyläther identisch sein dürfte. Die Synthese des Xanthohumol‐dimethyläthers (Kondensation von 3‐[γ.γ‐Dimethyl‐allyl]‐phloracetophenon‐4.6‐dimethyläther mit Anisaldehyd) steht in Einklang mit der Konstitution des Xanthohumols als 4.2′.6′‐Trihydroxy‐4′‐methoxy‐3′‐[γ.γ‐dimethyl‐allyl]‐chalkon.
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