The Luminescence Properties of Some Ruthenium(II) Complexes and Solid Dye Films in Relation to Their Application in Photoelectrochemical Cells

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jul 1982 English Publisher:WileyJournal:Berichte der Bunsengesellschaft für physikalische Chemie, volume 86, pages 676-680 (issn: 0005-9021, eissn: 0005-9021,

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Authors: P. A. Breddels; G. Blasse;

doi: 10.1002/bbpc.19820860720

The Luminescence Properties of Some Ruthenium(II) Complexes and Solid Dye Films in Relation to Their Application in Photoelectrochemical Cells

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Abstract

AbstractEnergy transfer phenomena in Ru(bpy)3(ClO4)2 are investigated in order to estimate the optimum layer thickness when this complex is used as a sensitizer on a semiconductor electrode in a photoelectrochemical cell. The optimum thickness appeared to be about five molecular layers. We also examined the luminescence properties of solid dye films of some Ru(bpy)2+3 complexes. It is shown that the luminescence intensity can be used as a probe for studying the behaviour of the light‐sensitive electrode in a photoelectrochemical cell.

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