Analysis of the Thermodynamic Behavior of Hydrogen in Body‐Centered‐Cubic Metals with Application to Niobium‐Hydrogen

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Dec 1972 English Publisher:WileyJournal:Berichte der Bunsengesellschaft für physikalische Chemie, volume 76, pages 1,278-1,282 (issn: 0005-9021, eissn: 0005-9021,

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Authors: M. O'keeffe; S. A. Steward;

doi: 10.1002/bbpc.19720761217

Analysis of the Thermodynamic Behavior of Hydrogen in Body‐Centered‐Cubic Metals with Application to Niobium‐Hydrogen

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Abstract

AbstractA critical analysis of experimental data for the Nb‐H system shows that the partial molar entropy data are best interpreted by assuming a random solution of hydrogen in the metal on one site per metal atom even in concentrated solutions. A possible geometrical interpretation of this result is suggested.

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