AbstractIn this study, we aimed to evaluate the characteristics of curaua composites using dynamic mechanical analysis. Curaua composites with distinct fiber volume fractions (11–38%) were studied, and their storage and loss moduli were found to increase with reinforcement content. On the other hand, the activation energy of the relaxation process in the glass‐transition region decreased with the curaua content; this conclusion was corroborated by the elastic chain concentration results. The Cole–Cole plots became flattened as the curaua content increased; this was indicative of a more homogeneous system, and the tan δ peak height and peak width at half‐height decreased. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012