Crosslink reaction of natural rubber with thiuram sulphur donors in the presence of a thiuram monosulfide

descriptionPublicationkeyboard_double_arrow_right Article 10 May 2002 English Publisher:WileyJournal:Journal of Applied Polymer Science, volume 85, pages 491-499 (issn: 0021-8995, eissn: 1097-4628,

Copyright policy )

Authors: González Hernández, Luis; Rodríguez-Díaz, Andrés; Campo, Aránzazu del; Marcos-Fernández, Ángel;

doi: 10.1002/app.10438

handle: 10261/34198

Crosslink reaction of natural rubber with thiuram sulphur donors in the presence of a thiuram monosulfide

- Summary
- Subjects
- Metrics

Abstract

AbstractThe vulcanization of natural rubber was studied with the sulfurating agents dipentamethylene thiuram tetrasulfide (DPTT) and tetramethylene thiuram disulfide (TMTD) in the presence of tetramethyl thiuram monosulfide (TMTM). This last accelerant affects the rate and efficiency of the vulcanization as well as the structures of crosslinks formed by the two sulphur donors. It may give rise to a polymerization between adjacent double bonds and generate a inhomogeneous crosslink distribution with an adverse effect on physical properties. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 491–499, 2002

Related Organizations

Keywords

Crosslinking, Mechanical properties, Rubber, Networks

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	15
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Top 10%
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average