Metal‐Free Aryltrifluoromethylation of Activated Alkenes

descriptionPublicationkeyboard_double_arrow_right Article 31 Oct 2013 Switzerland English Publisher:WileyJournal:Angewandte Chemie International Edition, volume 52, pages 13,086-13,090 (issn: 1433-7851, eissn: 1521-3773,

Copyright policy )Funded by:EC | NIGOCAT

Authors: Kong, Wangqing; Casimiro, Maria; Fuentes, Noelia; Merino, Estíbaliz; Nevado, Cristina;

doi: 10.1002/anie.201307377 , 10.1002/ange.201307377

pmid: 24174281

Metal‐Free Aryltrifluoromethylation of Activated Alkenes

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Abstract

Metal-free: The first metal-free aryltrifluoromethylation of activated alkenes has been developed. With this method, trifluoromethylated isoquinolinediones, spirobicycles, oxindoles, and α-aryl-β-trifluoromethylamides were obtained with high control of the regioselectivity.

Country

Switzerland

Related Organizations

University of Zurich
Switzerland

Keywords

10120 Department of Chemistry, arenes, alkenes, 1503 Catalysis, Togni reagent, iodine, 540 Chemistry, trifluoromethylation, 1600 General Chemistry

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