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A Hexanuclear Iridium Chain

descriptionPublicationkeyboard_double_arrow_right Article 30 Jan 2003 Spain English Publisher:WileyJournal:Angewandte Chemie International Edition, volume 42, pages 529-532 (issn: 1433-7851, eissn: 1521-3773,

Authors: Tejel, Cristina; Ciriano, Miguel A.; Villarroya, B. Eva; López, José A.; Lahoz, Fernando J.; Oro, Luis A.;

doi: 10.1002/anie.200390152 , 10.1002/ange.200390120

pmid: 12569481

handle: 10261/270892

A Hexanuclear Iridium Chain

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Abstract

Electrons in chains: A novel metallic chain made up of six iridium atoms (see picture) with an average oxidation state of +1.33 has been found in the complex HH,HT,HH-[Ir6(μ-OPy)6(I)2(CO)12] (Opy=2-pyridonate, H=head, T=tail). This complex provides a new link in the electronic sequence connecting dinuclear IrI and IrII complexes. Peer reviewed

Country

Spain

Related Organizations

Aragón Materials Science Institute
Spain
Spanish National Research Council
Spain
University of Zaragoza
Spain

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	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	66
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	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%