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Properties of Sulfur‐Sulfur Bonds

Name: Properties of Sulfur‐Sulfur Bonds
Creator: Ralf Steudel
Keywords: 01 natural sciences, 3. Good health, 0104 chemical sciences

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1975 English Publisher:WileyJournal:Angewandte Chemie International Edition in English, volume 14, pages 655-664 (issn: 0570-0833,

Authors: Ralf Steudel;

doi: 10.1002/anie.197506551

Properties of Sulfur‐Sulfur Bonds

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Abstract

AbstractSS bonds are extraordinarily flexible and have properties that are observed only on isolated occasions for other homonuclear bonds: the bond lengths very between 1.8 and 3.0Å, the bond angles between 90 and 180° and the dihedral angles between 0 and 180°; the bond energies amount to up to 430 kJ/mol. The SS stretching frequencies can appear over the range 177–820 cm−1 and force constants of 1.4 to 6.3 mdyne/Å have been calculated. This variability is illustrated with examples containing isolated and cumulated SS bonds.

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