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Angewandte Chemie
Article . 2012 . Peer-reviewed
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https://dx.doi.org/10.5451/uni...
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Article . 2012
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Structure‐Selective Catalytic Alkylation of DNA and RNA

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 22 Oct 2012Embargo end date: 01 Jan 2012 Switzerland German Publisher:WileyJournal:Angewandte Chemie, volume 124, pages 12,166-12,170 (issn: 0044-8249, eissn: 1521-3757, Copyright policy )
Authors: Tishinov, Kiril; Schmidt, Kristina; Häussinger, Daniel; Gillingham, Dennis;

doi: 10.1002/ange.201205201 , 10.1002/anie.201205201 , 10.5451/unibas-ep24381

pmid: 23090851

Structure‐Selective Catalytic Alkylation of DNA and RNA

Abstract

A variety of nucleic acids can be catalytically alkylated with rhodium-carbenoids generated from diazo compounds in aqueous buffer through an NH insertion process (see scheme; MES=2-(N-morpholino)ethanesulfonic acid). The method specifically targets unpaired bases such as those present in single strands, turn regions, and overhangs while leaving double-stranded sequences untouched.

Country
Switzerland
Related Organizations
Keywords

Structure-Activity Relationship, Alkylation, Nucleic Acid Conformation, RNA, Rhodium, DNA, Catalysis, Substrate Specificity

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    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
46
Top 10%
Top 10%
Top 10%
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