Dynamical Behavior and Dipole–Dipole Interactions of Tetrafluoromethane–Water

descriptionPublicationkeyboard_double_arrow_right Article 10 Oct 2006 Italy German Publisher:WileyJournal:Angewandte Chemie, volume 118, pages 6,863-6,866 (issn: 0044-8249, eissn: 1521-3757,

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Authors: CAMINATI, WALTHER; MARIS, ASSIMO; A. Dell’Erba; P. G. Favero;

doi: 10.1002/ange.200602000 , 10.1002/anie.200602000

pmid: 16977658

handle: 11585/30405

Dynamical Behavior and Dipole–Dipole Interactions of Tetrafluoromethane–Water

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Abstract

Water and tetrafluoromethane form a stable complex with a O×××F contact rather than a O-H×××F interaction, according to the rotational spectra of several isotopologues of the complex observed in supersonic expansions. All of these spectra display the features of a symmetric top.

Country

Italy

Related Organizations

Instituto Politécnico Nacional
Mexico
Alma Mater Studiorum University of Bologna
Italy
Polytechnic University of Bari
Italy

Keywords

PROTONPHOBIC INTERACTIONS; MOLECULAR COMPLEXES; MOLECULAR DYNAMICS; ROTATIONAL SPECTROSCOPY IN SUPERSONIC JETS; WATER-FREONS

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