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Band Tailoring Enabled Perovskite Devices for X‐Ray to Near‐Infrared Photodetection

Authors: Yi‐Chu He; Guan‐Hua Dun; Jun Deng; Jia‐Li Peng; Ken Qin; Jia‐He Zhang; Xiang‐Shun Geng; +8 Authors

Band Tailoring Enabled Perovskite Devices for X‐Ray to Near‐Infrared Photodetection

Abstract

AbstractPerovskite semiconductors have shown significant promise for photodetection due to their low effective carrier masses and long carrier lifetimes. However, achieving balanced detection across a broad spectrum—from X‐rays to infrared—within a single perovskite photodetector presents challenges. These challenges stem from conflicting requirements for different wavelength ranges, such as the narrow bandgap needed for infrared detection and the low dark current necessary for X‐ray sensitivity. To address this, this study have designed a type‐II FAPbI3 perovskite‐based heterojunction featuring a large energy band offset utilizing narrow bandgap tellurium (Te) semiconductor. This innovative design broadens the detection range into the infrared while simultaneously reducing dark current noise. As‐designed device allows for the detection of near infrared band, achieving a detectivity of 6.8 × 109 Jones at 1550 nm. The low dark current enables X‐ray sensitivity of up to 1885.1 µC Gy⁻¹ cm⁻2. First‐principles calculations confirm the type‐II band structure alignment of the heterojunction, and a self‐driven response behavior is realized. Moreover, this study have developed a scalable 40 × 1 sensor array, demonstrating the potential for wide‐spectrum imaging applications. This work is expected to advance the application of perovskite‐based wide‐spectrum devices.

Related Organizations
Keywords

heterojunction, X‐ray to Infrared, Science, Te/FAPbI3 photodetector, Q, wide‐ spectrum, band tailoring, Research Article

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Top 10%
Average
Top 10%
Green
gold