AbstractThe use of metal–organic frameworks (MOFs) in solid‐state electrolytes (SSEs) has been a very attractive research area that has received widespread attention in the modern world. SSEs can be divided into different types, some of which can be combined with MOFs to improve the electrochemical performance of the batteries by taking advantage of the high surface area and high porosity of MOFs. However, it also faces many serious problems and challenges. In this review, different types of SSEs are classified and the changes in these electrolytes after the addition of MOFs are described. Afterward, these SSEs with MOFs attached are introduced for different types of battery applications and the effects of these SSEs combined with MOFs on the electrochemical performance of the cells are described. Finally, some challenges faced by MOFs materials in batteries applications are presented, then some solutions to the problems and development expectations of MOFs are given.