Introduction: Properties, Preparation, Overview of Application Metal-Catalyzed Borylation of C-X and C-H Bonds for the Synthesis of Boronic Esters Transition-Metal Catalyzed Sila- and Diborylation of Alkenes, Allenes, and Alkynes The Contemporary Suzuki-Miyaura Reaction Rhodium and Palladium-Catalyzed Asymmetric Conjugate Additions of Organoboronic Acids Recent Advances in Chan-Lam Coupling Reaction: Copper-Promoted C-Heteroatom Bond Cross-Coupling Reactions with Boronic Acids and Derivatives Transition-Metal Catalyzed Desulfitative Coupling of Thioorganic Compounds with Boronic Acids Catalytic Additions of Allylic Boronates to Carbonyl and Imine Derivatives Recent Advances in Nucleophilic Addition Reactions of Organoboronic Acids and their Derivatives to Unsaturated C?N Functionalities Asymmetric Homologation of Boronic Esters with Lithiated Carbamates Organotrifluoroborates: Organoboron Reagents for the 21st Century Boronic Acids as Catalysts Applications of boronic acids in chemical biology and medicinal chemistry Boronic Acids in Materials Chemistry