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Supercritical Carbon Dioxide

Authors: S. Mayadevi;

Supercritical Carbon Dioxide

Abstract

Carbon dioxide, dry ice (solid phase) [124-38-9] CO2 (MW 44.01) InChI = 1S/CO2/c2-1-3 InChIKey = CURLTUGMZLYLDI-UHFFFAOYSA-N (supercritical carbon dioxide is used as a solvent, reagent, and reaction medium) Physical Data mp: −56.6 °C; bp: −78.5 °C (sublimes); density: 1.977 kg m−3 (gas at 1 bar and 0 °C); crystal structure: trigonal; molecular shape: linear; critical point: Tc: 31 °C; Pc: 73.825 bar; ρc: 464 kg m−3; triple point: temperature: −56.6 °C, pressure: 5.185 bar; latent heat: 46.84 kcal kg−1 (fusion, 1.013 bar, triple point), 136.40 kcal kg−1 (vaporization, 1.013 bar, boiling point); exposure limits in air: threshold limit value (TLV): 5000 ppm; short-term exposure limit (STEL): 30 000 ppm; immediately dangerous to life or health (IDLH): 40 000 ppm. Solubility soluble in water, ethanol, and acetone. Form Supplied in liquid in equilibrium with gas under pressure; dry ice (solid). Handling, Storage, and Precautions colorless gas/liquid or white solid (dry ice). It is noninflammable, inert in most environments. At concentrations between 2 and 10%, it can cause nausea, dizziness, headache, increased blood pressure, and respiratory rate. Forms carbonic acid with moisture in air and leads to irritation of the eyes. At concentrations above 10%, it is an asphyxiant and cerebral vasodilator. Cylinders must be stored in dry, ventilated areas, away from heat sources and direct sunlight.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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