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Effect of heat treatment on the molecular mobility in the triacylglycerol

Effect of heat treatment on the molecular mobility in the triacylglycerol

Abstract

Relevance of the work is caused by the widespread introduction of new technologies in the food industry processes, requiring the use of modern techniques for the quality analysis of products at all stages of their processing and storage. Therefore, the purpose of the paper is to study the physicochemical properties of refined sunflower oil to select rational modes of cooking healthy foods.Thermophysical and dielectric properties of a number of refined sunflower oil samples with different thermal history were investigated. The samples were kept in an air thermostat at isobaric conditions at heat treatment temperature of 433K. Temperature dependences of oil specific heat in the temperature range 173 - 423K were obtained by the thermophysical method on dynamic calorimeter with a heating rate of 3K/min. Complex permittivity of oil samples in the temperature range 173 - 323K at frequencies f = 1, 5, 10, 50kHz was studied using an automated system based on AC Bridge R5083.Molecular mobility and nature of relaxation and phase transitions was considered and, based on this, the changes in the structure and chemical composition of sunflower oil as a result of heating in the normal use conditions were studied. This is of great applied importance since under these conditions (at T > 373K in air) processes of thermal and thermooxidative degradation of oil with the formation of harmful substances (fatty acid peroxides, acrolein, etc.) that can go into food are possible.

Исследованы теплофизические и диэлектрические свойства рафинированного подсолнечного масла с различной термической предысторией. Рассмотрена природа релаксационных и фазовых переходов, наблюдавшихся на температурных зависимостях удельной теплоемкости и комплексной диэлектрической проницаемости. На основе этого изучены изменения структуры и химического состава подсолнечного масла в результате ее нагрева в условиях обычного использования. 

Досліджені теплофізичні та діелектричні властивості рафінованої соняшникової олії з різною термічною передісторією. Розглянута природа релаксаційних та фазових переходів, що спостерігалися на температурних залежностях питомої теплоємності і комплексної діелектричної проникності. На основі цього вивчено зміни структури та хімічного складу соняшникової олії у результаті її нагрівання в умовах звичайного використання. 

Keywords

триацилгліцерин; питома теплоємність; комплексна діелектрична проникність; релаксаційний перехід; фазовий перехід, triacylglycerol; specific heat; complex permittivity; relaxation transition; phase transition, УДК 539.213:664.315.6.014, триацилглицерин; удельная теплоемкость; комплексная диэлектрическая проницаемость; релаксационный переход; фазовый переход

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold