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Термодинамічні розрахунки реакцій синтезу славсоніту

Authors: Lisachuk, Georgij; Fedorenko, Olena; Kryvobok, Ruslan; Zakharov, Artem;

Термодинамічні розрахунки реакцій синтезу славсоніту

Abstract

В статье представлены результаты расчетов термодинамических констант тройных соединений системы SrO-Al2O3-SiO2. Также методом термодинамических расчетов, на основе полученных данных, установлено вероятность протекания реакции образования славсонита при использовании различных сырьевых компонентов. Проведенные расчеты свидетельствуют о том, что перспективными сырьевыми компонентами для низкотемпературного синтеза славсонита является карбонат стронция и каолин, вероятность протекания реакции возможна начиная с температуры 200 °С

The article presents the results of calculations of the thermodynamic constants of ternary compounds of the SrO-Al2O3-SiO2 system. Also, using the method of thermodynamic calculations, based on the obtained data, the occurrence probability of the slavsonite formation reaction using various raw materials is established. The calculations show that strontium carbonate and kaolin are promising raw materials for low-temperature synthesis of slavsonite, the probability of a reaction is possible starting from a temperature of 200 °C

В статті представлені результати розрахунків термодинамічних констант потрійних сполук системи SrO-Al2O3-SiO2. Також методом термодинамічних розрахунків, на основі отриманих даних, встановлено ймовірність протікання реакції утворення славсоніту при використанні різних сировинних компонентів. Проведені розрахунки свідчать про те, що перспективними сировинними компонентами для низькотемпературного синтезу славсоніту є карбонат стронцію і каолін, ймовірність протікання реакції можлива починаючи з температури 200 °С

Keywords

славсонит; стронциевый анортит; Sr-геленит; низкотемпературный синтез; энтальпия; энтропия; теплоемкость; энергия Гиббса, УДК 666.651, slavsonite; strontium anorthite; Sr-helenite; low-temperature synthesis; enthalpy; entropy; heat capacity; Gibbs energy, славсоніт; стронцієвий анортит; Sr-геленіт; низькотемпературний синтез; ентальпія; ентропія; теплоємність; енергія Гіббса

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold