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Evaluation of the efficiency of inhibitor protection of metal surfaces in aggressive water and oil environments

Evaluation of the efficiency of inhibitor protection of metal surfaces in aggressive water and oil environments

Abstract

The article analyzes the problems associated with the occurrence of corrosion processes of equipment during oil and gas production. The main anti-corrosion methods and means used in modern conditions are considered. In the vast majority of cases, the corrosion of industrial equipment proceeds by an electrochemical mechanism when the metal is in contact with an aqueous mineralized environment, therefore it is advisable to use the inhibitory protection of the equipment against corrosion processes. It is known that corrosion inhibitors are substances, the introduction of which in relatively small quantities into an aggressive environment causes a noticeable slowing down of metal corrosion. In fact, it is a substance that inhibits the corrosion process due to competitive adsorption with particles of activators and the formation of protective adsorption or phase films on the metal surface, sometimes with barrier properties. Corrosion inhibitors affect the kinetics of electrode processes that occur during corrosion, and are also characterized by the ability to form oxide, hydroxide or other films on the metal and transfer the metal to a passive state. Taking into account the mechanism and conditions of corrosion processes during the extraction and transportation of oil-containing products and gas condensate, a chemical method of equipment protection was chosen for research. Known inhibitors based on phosphonic acids, as well as synthesized substances based on sulfonates, imidazolines, and diamines, were used as chemical agents in the research. As a result of the research, the effectiveness of protecting metals from corrosion was evaluated depending on the composition of the highly mineralized environment, the type of metal, the type of inhibitor and its concentration, and the effectiveness of the developed scale stabilizer (sodium nitrile dimethyl sulfonate) was evaluated in comparison with known reagents. It is shown that the effectiveness of protecting metals from corrosion in water-oil mixtures using alkylimidazoline inhibitors and inhibitors developed on the basis of sunflower oil and polyalkylene polyamine (AC-1), ethylenediamine (AC-2) reaches 90% in doses of 5 - 50 mg/dm3.

В даній роботі було детально досліджено ефективності інгібування корозійних процесів в агресивних водно-нафтових середовищах. За допомогою масометричного методу визначено ефективність інгібування та швидкість протікання корозії. Визначено, що на швидкість протікання процесу корозії впливає мінеральний склад розчину та склад кородуючого металу. Результати показують, що нафта хоч і знижує швидкість корозії за рахунок утворення плівки на поверхні металу, але при підвищенні вмісту карбонових кислот наявність нафти ніяким чином не впливає на швидкість корозії.

Keywords

нафтовмісні середовища, inhibitor protection, oil-containing media, alkylimidozoline, інгібіторний захист, metal corrosion, корозія металів, алкілімідозолін

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold