Five samples of luminophores, activated by europium and synthesized by sol-gel and СВС methods were investigated. The researched samples have basic surface character, differing depending on the base of luminophor and percentage of europium. Excitation and photoluminescent spectra were obtained. Photoluminescent spectrum of the samples, containing Eu(III) ions have the similar character. They have 5 stripes with maximum at 580, 598, 622, 658 nm and the doublet with stripes at 702 and 706 nm which are referred to innerconfigurational 4f-4f transits if europium ion 7F0-5D4. The samples YVPO4(P10):Eu8% and YVO4:Eu10% have the most intense luminescence. Their intensity is about 60 times higher than the YPO4:Eu10% sample has.