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Связь феноменологических и физико-химических моделей аналитических сигналов в инверсионной вольтамперометрии

Связь феноменологических и физико-химических моделей аналитических сигналов в инверсионной вольтамперометрии

Abstract

Исследована связь феноменологических и физико-химических моделей аналитических сигналов в инверсионной вольтамперометрии. В качестве теоретической выбрана модель обратимого анодного и катодного электродных процессов на ртутно-пленочном электроде при линейном изменении потенциала. Общепринятым приемом представления физико-химических моделей в вольтамперометрии является использование безразмерного параметра (H), в который входит скорость развертки потенциала, толщина электрода, коэффициент диффузии вещества, число передаваемых электронов и температура. Для описания теоретических пиков сконструированной феноменологическая функция произведения двух встречных логист с пятью эмпирическими коэффициентами. Установлены простые взаимосвязи параметра H с эмпирическими параметрами функции произведения двух встречных логист.

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Keywords

инверсионная вольтамперометрия, анодные процессы, феноменологические модели, феноменологическая функция, линейные изменения, вещества, электродные процессы, безразмерные параметры, скорость, катодные процессы, потенциалы, диффузия, аналитические сигналы, коэффициенты, теоретические модели, толщина, температура, физико-химические модели, развертки, ртутно-пленочные электроды, логист, электроны, взаимосвязи

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    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green