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Перспективы использования тетрафторброматов щелочных и щелочно-земельных металлов в синтезе соединений поливалентного йода для "зеленой" химии

Перспективы использования тетрафторброматов щелочных и щелочно-земельных металлов в синтезе соединений поливалентного йода для "зеленой" химии

Abstract

В данной работе представлен литературный обзор работ по развитию химии поливалентного йода, а именно использование соединений поливалентного йода в «зеленой» химии как экологически безопасных окислителей, методы использования и синтез которых являются менее энергозатратными по сравнению с существующими аналогами. Приведен литературный обзор по структуре и реакционной способности тетрафторброматов щелочных и щелочно-земельных металлов по отношению к органическим соединениям, рассмотрены предпосылки использования тетрафторброматов в синтезе соединений поливалентного йода, а также предложен вариант синтеза фторпроизводных соединений поливалентного йода с использованием тетрафторброматов щелочных и щелочно-земельных металлов.

In this paper, we present a literature review of the development of polyvalent iodine chemistry , namely the use of polyvalent iodine compounds in ''green'' chemistry as environmentally safe oxidants, the methods of use and synthesis of which are less energy-consuming compared to existing analogues. A literature review on the structure and reactivity of tetrafluorobromates of alkaline and alkaline earth metals with respect to organic compounds is given, preconditions for the use of tetrafluorobromates in the synthesis of polyvalent iodine compounds are considered, and a variant of the synthesis of fluorine derivatives of polyvalent iodine using tetrafluorobromates of alkali and alkaline earth metals is proposed.

Country
Russian Federation
Related Organizations
Keywords

щелочные металлы, поливалентный иод, окислители, органические соединения, щелочно-земельные металлы

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green