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Article . 2015
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Моделирование процесса гидрирования высших алкадиенов с учетом селективного осернения катализатора

descriptionPublicationkeyboard_double_arrow_right Article 20 Nov 2015 Russian Publisher:Томский политехнический университет

Моделирование процесса гидрирования высших алкадиенов с учетом селективного осернения катализатора

Abstract

Рассмотрены термодинамические и кинетические закономерности превращения серосодержащих соединений на катализаторе гидрирования высших алкадиенов, оценены константы равновесия реакций. Учет в модели влияния дозированного осернения никелевого контакта позволил определить количество остаточного содержания серы в зависимости от температуры в реакторе, от расхода водорода и влажности сырья. Pассчитаны оптимальные условия ведения промышленного процесса и выполнена оценка экономической эффективности от перехода на оптимальный режим.

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Keywords

селективное осернение, расход, водород, экономическая эффективность, моделирование, влажность, равновесие, реакторы, оптимальные условия, высшие алкадиены, кинетические закономерности, катализаторы, температура, термодинамические закономерности, сырье, промышленные процессы, серосодержащие соединения, оптимальные режимы, гидрирование, константы, сера, реакции

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    popularity
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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    		 Average
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green