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Синтез полиакрилонитрила в присутствии димера циклопентадиенилдикарбонилжелеза

Синтез полиакрилонитрила в присутствии димера циклопентадиенилдикарбонилжелеза

Abstract

Показано, что композиция на основе димера циклопентадиенилдикарбонилжелеза [CpFe(CO)2]2 и четыреххлористого углерода является эффективным инициатором полимеризации акрилонитрила и позволяет модифицировать молекулярно-массовые характеристики полиакрилонитрила, синтезируемого в условиях радикального инициирования. Установлено, что выбор растворителя и его концентрация играют определяющую роль в формировании полимера определенной молекулярной массы.

The composition of cyclopentadienyldicarbonyliron dimer [CpFe(CO)2]2 and carbon tetrachloride has been shown to be an active initiator of radical polymerization of acrylonitrile which allows modifying molecular weight characteristics of synthesized polyacrylonitrile. The choice of solvent and its concentration have been found to play a decisive role in the formation of polymers with a certain molecular weight.

Keywords

ЦИКЛОПЕНТАДИЕНИЛДИКАРБОНИЛЖЕЛЕЗА, ПОЛИМЕРИЗАЦИЯ, ПОЛИАКРИЛОНИТРИЛ, МОЛЕКУЛЯРНО-МАССОВЫЕ ХАРАКТЕРИСТИКИ

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
bronze
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