
The analysis of impact of various components for overall assessment of thermodynamic stability of complex compound is presented. The Born-Gaber cycle for determination of enthalpy formation of lanthanide borohydrides is made. By means of semiempirical method the complete data on formation enthalpy of gaseous ions of lanthanides is calculated. The change regularity of this value within lanthanides group is defined.
Приведён анализ влияния отдельных компонентов для общей оценки термодинамической устойчивости сложных соединений. Составлен цикл Борна-Габера для определения энтальпии образования борогидридов лантаноидов. Полуэмпирическим методом рассчитаны и получены полные сведения об энтальпии образования газообразных ионов лантаноидов. Установлена закономерность изменения этой величины в пределах группы лантаноидов.
ТЕРМОДИНАМИЧЕСКАЯ УСТОЙЧИВОСТЬ,ЭНТАЛЬПИЯ ОБРАЗОВАНИЯ,БОРОГИДРИДЫ ЛАНТАНОИДОВ,ЦИКЛ БОРНА-ГАБЕРА,THERMODYNAMIC STABILITY,FORMATION ENTHALPY,LANTHANIDE BOROHYDRIDES,BORN-GABER CYCLE
ТЕРМОДИНАМИЧЕСКАЯ УСТОЙЧИВОСТЬ,ЭНТАЛЬПИЯ ОБРАЗОВАНИЯ,БОРОГИДРИДЫ ЛАНТАНОИДОВ,ЦИКЛ БОРНА-ГАБЕРА,THERMODYNAMIC STABILITY,FORMATION ENTHALPY,LANTHANIDE BOROHYDRIDES,BORN-GABER CYCLE
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