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Системный анализ энтальпии образования газообразных ионов лантаноидов

Системный анализ энтальпии образования газообразных ионов лантаноидов

Abstract

The analysis of impact of various components for overall assessment of thermodynamic stability of complex compound is presented. The Born-Gaber cycle for determination of enthalpy formation of lanthanide borohydrides is made. By means of semiempirical method the complete data on formation enthalpy of gaseous ions of lanthanides is calculated. The change regularity of this value within lanthanides group is defined.

Приведён анализ влияния отдельных компонентов для общей оценки термодинамической устойчивости сложных соединений. Составлен цикл Борна-Габера для определения энтальпии образования борогидридов лантаноидов. Полуэмпирическим методом рассчитаны и получены полные сведения об энтальпии образования газообразных ионов лантаноидов. Установлена закономерность изменения этой величины в пределах группы лантаноидов.

Keywords

ТЕРМОДИНАМИЧЕСКАЯ УСТОЙЧИВОСТЬ,ЭНТАЛЬПИЯ ОБРАЗОВАНИЯ,БОРОГИДРИДЫ ЛАНТАНОИДОВ,ЦИКЛ БОРНА-ГАБЕРА,THERMODYNAMIC STABILITY,FORMATION ENTHALPY,LANTHANIDE BOROHYDRIDES,BORN-GABER CYCLE

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
bronze