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Описание калорических свойств н-алканов на основе сферически-симметричного потенциала Леннард-Джонса

Описание калорических свойств н-алканов на основе сферически-симметричного потенциала Леннард-Джонса

Abstract

На основе теории интегральных уравнений для частичных функций распределения проводились исследования точности определения изобарной теплоемкости н-алканов (метан, этан, бутан). Межмолекулярное взаимодействие в системах описывалось с помощью модельного сферически-симметричного потенциала Леннард-Джонса. Расчеты проведены в газовой, жидкой и сверхкритических областях. Полученные результаты хорошо согласуются с экспериментальными данными.On the basis of the theory of the integrated equations for partial functions of distribution the researches isobaric heat capacity of n-alkanes (methane, ethane, butane) were carried out. The intermolecular interaction in systems was described by means of the modelling spherically symmetric potential Lennard-Jones. Calculations are lead in gas, liquid and supercritical state. Obtained data good accuracy with experimental data.

Keywords

Н-АЛКАНЫ, ИЗОБАРНАЯ ТЕПЛОЕМКОСТЬ, ПОТЕНЦИАЛ ЛЕННАРД-ДЖОНСА

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold