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Учёные записки Казанского университета: Серия Естественные науки
Article . 2012
Data sources: CyberLeninka - Russian open access scientific library
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Препараты пирафен, мелафен и входящие в их состав компоненты в реакции с хлоридом меди(II) в солянокислой среде

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2012 Russian Publisher:Федеральное государственное автономное образовательное учреждение высшего образования «Казанский (Приволжский) федеральный университет»Journal:Ученые записки Казанского университета. Серия Естественные науки (issn: 2542-064X, eissn: 2500-218Х, Copyright policy )

Препараты пирафен, мелафен и входящие в их состав компоненты в реакции с хлоридом меди(II) в солянокислой среде

Abstract

Исследовано взаимодействие хлорида меди(II) с препаратами мелафен, пирафен и входящими в состав препаратов азотистыми основаниями, а также с бис(оксиметил)фосфиновой кислотой в солянокислой среде. Установлена структура тетрахлорокупрата(II) дипротонированного 2,4,6-триаминопиримидина методом рентгеноструктурного анализа. Показано что меламин, 2,4,6-триаминопиримидин и бис(оксиметил)фосфиновая кислота не склонны выступать в роли внутрисферных лигандов.The interaction of copper(II) chloride with melafene and pirafene drugs, nitrogen bases included in their composition, and also bis(oxymethyl)phosphinic acid in a chloride medium is investigated. The structure of diprotonated 2,4,6-triaminopyrimidine tetrachlorocuprate(II) is established by X-ray crystallography. It is shown that melamine, 2,4,6-triaminopyrimidine and bix(oxymethyl)phosphinic acid do not tend to form inner-sphere complexes.

Keywords

ПИРАФЕН, МЕЛАФЕН, БИС(ОКСИМЕТИЛ)ФОСФИНОВАЯ КИСЛОТА, 6-ТРИАМИНОПИРИМИДИН, МЕЛАМИН, ХЛОРОВОДОРОДНАЯ КИСЛОТА, ПРОТОНИРОВАННЫЕ ФОРМЫ, МЕДЬ(II), КОМПЛЕКСООБРАЗОВАНИЕ, РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ, BIS(OXYMETHYL)PHOSPHINIC ACID, COPPER(II)

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
gold