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Прогнозирование состава твердых растворов CdxPb1–xS моделированием процесса соосаждения сульфидов свинца и кадмия

Authors: Kirsanov, A. Y.; Markov, V. F.; Maskaeva, L. N.;

Прогнозирование состава твердых растворов CdxPb1–xS моделированием процесса соосаждения сульфидов свинца и кадмия

Abstract

В работе исследована возможность интеркаляции тиодиацетат-анионов в структуру магний-алюминиевых слоистых двойных гидроксидов методом соосаждения и методом анионного обмена. Методом рентгенофазового анализа и КР-спектроскопии показано, что тиодиацетат-анионы внедряются в межслоевое пространство СДГ. Полученные материалы представляют интерес как сорбенты для ионов тяжелых металлов. In the present paper the author has elaborated a model, which provides prognostication forecasting of solid solution CdxPb1−xS composition at co-precipitation of individual lead and cadmium sulphides. It has been shown that content of CdS in a solid solution has extreme characteristics depending on lead Pb2+ and cadmium Cd2+ ion concentration in a reactor. Satisfactory correlation of simulation results with experimental data, obtained by X-ray analysis of the synthesized films, has been proved. Kirsanov Aleksey Yurevich – Postgraduate Student, Physical and Colloid Chemistry Subdepartment, Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002. Кирсанов Алексей Юрьевич – аспирант, кафедра «Физическая и коллоидная химия», ФГАОУ ВПО «УрФУ имени первого Президента России Б.Н. Ельцина». 620002, г. Екатеринбург, ул. Мира 28. E-mail: alexk_ft@mail.ru Markov Vyacheslav Filippovich – Dr. Sc. (Chemistry), Professor, Physical and Colloid Chemistry Subdepartment, Ural Federal University named after the first President of Russia B.N. Yeltsin. 28, Mira street, Ekaterinburg, 620002. Марков Вячеслав Филиппович – доктор химических наук, профессор, кафедра «Физическая и коллоидная химия», ФГАОУ ВПО «УрФУ имени первого Президента России Б.Н. Ельцина». 620002, г. Екатеринбург, ул. Мира 28. E-mail: vfmarkov@list.ru Maskaeva Larisa Nikolaevna – Dr. Sc. (Chemistry), Professor, Physical and Colloid Chemistry Subdepartment, Ural Federal University named after the first President of Russia B.N.Yeltsin. 28, Mira street, Ekaterinburg, 620002. Маскаева Лариса Николаевна – доктор химических наук, профессор, кафедра «Физическая и коллоидная химия», ФГАОУ ВПО «УрФУ имени первого Президента России Б.Н. Ельцина». 620002, г. Екатеринбург, ул. Мира 28. E-mail: mln@urаl.ru

Keywords

сульфид свинца, УДК 546.815, computer simulation, компьютерное моделирование, lead sulfide, solid solution, твердый раствор, ГРНТИ 31.17, гидрохимическое осаждение, cadmium sulfide, hydrochemical precipitation, сульфид кадмия

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green