Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

Korenev V.; Abramov P.; Kompankov N.; Gushchin A.; Sheven D.; Sokolov M.

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Национальный агрегатор открытых репозиториев российских университетов (HOPA)

Article . 2018

Data sources: Национальный агрегатор открытых репозиториев российских университетов (HOPA)

Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2018

Authors: Korenev V.; Abramov P.; Kompankov N.; Gushchin A.; Sheven D.; Sokolov M.;

Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

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Abstract

© 2018 Elsevier B.V. A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

Keywords

Photoactivation, Electrochemistry, Areneruthenium complexes, Sulfide clusters

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