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Article . 2022 . Peer-reviewed
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OBTAINING LOW-MOLECULAR WEIGHT GALACTOMANNANES AND STUDYING THEIR PHYSICO-CHEMICAL CHARACTERISTICS

Authors: Dilnoza Mukhtarovna Amonova; Bakhtiyor Ikromovich Mukhitdinov; Abbaskhan Sabirkhanovich Turaev; Khusniddin Khasanbaevich Kirgizbayev; Azizbek Anvarzhanovich Boydedayev; Bobur Aktamovich Sindarov; Zhakhongir Nematullaevich Bekmirzayev;

OBTAINING LOW-MOLECULAR WEIGHT GALACTOMANNANES AND STUDYING THEIR PHYSICO-CHEMICAL CHARACTERISTICS

Abstract

The aim of this study was studying the effect of acidic hydrolysis conditions on the molecular parameters of galactomannan, such as weight average degree of polymerization (DPw), weight average molecular weight (Mw), product yield, depolymerization reaction rate, and mannose/galactose (Man/Gal) ratio in the presence of hydrochloric acid and obtaining low molecular weight oligogalactomannans soluble in water. A preparing possibility low molecular weight galactomannans by acid hydrolysis of guar galactomannan (DPw=1160, Mw=563.8 kDa, Man/Gal=1.89) in the presence of hydrochloric acid was studied. The studies were carried out in hydrochloric acid solutions with various concentrations (0.05–1.0 mol/L) for different times (10–240 min) at a constant temperature (80 °C). In the course of the studies, effects of the reaction conditions on the molecular parameters of the product obtained were analyzed. The conducted reactions yielded low molecular weight galactomannans and oligogalactomannans with different molecular parameters (DPw=6–1021, Mw=2.6–505.1 kDa, Man/Gal=1.90–3.19) and yields (2.8–97.1%). Based on the results obtained, the optimal reaction conditions (HCl 0.1 mol/L, 240 min, 80 °C) were supposed for the preparation of galactomannan oligosaccharides. The structural studies of the products indicated that products with reduced galactose residues could be prepared by this method.

Keywords

олигогалактоманнан, кислотный гидролиз, degree of polymerization, oligogalactomannan, деполимеризация, галактоманнан, galactomannan, depolymerization, acidic hydrolysis, степень полимеризации

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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