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The emergence of dissipative structures under non-equilibrium crystallization

Authors: Bereza, O. Y.;

The emergence of dissipative structures under non-equilibrium crystallization

Abstract

Abstract. This research is devoted to studying the structure forming phenomena in the systems with eutectic transformations under nonequilibrium conditions. It has been demonstrated that the dissipate structures form in the liquid and solid state under nonequilibrium phase transformation. This work also considers the matter of driving forces for crystallization processes under nonequilibrium conditions of cooling alloys of eutectic systems. Having analyzed heat processes, the author has proposed a structural model for a thin layer of smelt on the crystal-liquid boundary; and according to this model, convective processes result in occurrence of cellular liquid structures shaped as even hexahedrons. Excessive temperature cooling, which occurs in such cases in the cell centers and on their boundaries, is the driving force for crystallization. These cellulars are liquid dissipate structures under nonequilibrium conditions of phase transformations. Such model have been developed for two-phase crystallization. While considering the conditions of coupled crystal growth in different phases it has been demonstrated that quasieutectics are solid dissipate structures which formed in the non-eutectic alloy compositions and which had clear section boundary with main structure. The critical overcooling must be achieved for the formation of both types of structures. It has been shown that concurrent growth of phases and formation of colonial structures are feasible at average cooling rates, only provided at least one of the phases has an atomic-rough surface.

Анотація. Проблема впливу нерівноважних умов фазових перетворень на процеси та механізми формування структури сплавів є важливою і актуальною через значні зміни властивостей сплавів, що виникають. У роботі проаналізовано поведінку розплаву на передкристалізаційному етапі і в період фазових трансформацій під час нерівноважної кристалізації у сплавах евтектичного типу. Продмонстровано, що і в розплавленому, і в твердому стані виникають дисипативні структури, які мають особливу будову та впливають на механізми формування структури та властивості сплавів.

Аннотация. Проблема влияния неравновесных условий фазовых превращений на процессы и механизмы формирования структуры сплавов является важной и актуальной из-за возникающих значительных изменений их свойств. В работе проанализировано поведение расплава на передрекристаллизационном этапе и при фазовых трансформациях в ходе неравновесной кристаллизации в сплавах эвтектического типа. Показано, что и в расплаве, и в твердом состоянии возникают дисипативные структуры, которые имеют особое строение и влияют на механизмы их формирования и свойства сплавов.

Keywords

диссипативные структуры; неравновесная кристаллизация; эвтектические сплавы; граница жидкость-кристалл; квазиэвтектика, УДК 532.782, a dissipate structure; nonequilibrium crystallization; eutectic alloys; liquid- crystal boundary; quasieutectics, дисипативні структури; нерівноважна кристалізація; евтектичні сплави; межа рідина-кристал; квазіевтектика

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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