Synthesis, crystal structure and optical properties of 1,1'-(1,n-alkanediyl)bis(3-methylimidazolium) halobismuthates

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2018 Russian Federation English Publisher:Elsevier BVJournal:Journal of Molecular Structure, volume 1,151, pages 186-190 (issn: 0022-2860,

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Authors: Kotov, Vitalii Yu.; Baranchikov, Alexander E.; Ishmetova, Rashida I.; Rusinov, Gennady L.; Kozyukhin, Sergey A.; Ilyukhin, Andrey B.;

doi: 10.1016/j.molstruc.2017.09.040

Synthesis, crystal structure and optical properties of 1,1'-(1,n-alkanediyl)bis(3-methylimidazolium) halobismuthates

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Abstract

Abstract Four hybrid 3,3'-(alkane-1,n-di-yl)-bis(1-methyl- 1H- imidazole-3-ium) halobismuthates were prepared by a facile solution route and characterized by diffuse reflectance spectra and photoluminescence measurements. Crystal structure of 3,3'-(buthane-1,4-di-yl)-bis(1-methyl- 1H- imidazole-3-ium) bromobismuthate (1) contains zero-dimensional Bi 2 Br 10 anions. Crystal structure of 3,3'-(pentane-1,5-di-yl)-bis(1-methyl- 1H- imidazole-3-ium) iodobismuthate (4) contains zero-dimensional Bi 2 I 9 anions.

Country

Russian Federation

Related Organizations

National Research University of Electronic Technology
Russian Federation
NS Kurnakova Institute of General and Inorganic Chemistry
Russian Federation
Ural Federal University
Russian Federation
Russian Academy of Sciences
Russian Federation
Tomsk State Pedagogical University
Russian Federation

Keywords

люминесценция, диффузное отражение, фотолюминесценция, кристаллическая структура

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