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HAL-IRD
Article . 2025
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High Pressure Research
Article . 2025 . Peer-reviewed
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Simple method to determine equations of state of liquids in the 0–10 GPa range

Authors: Klotz, S.; Guarnelli, Y.; Murata, K.;

Simple method to determine equations of state of liquids in the 0–10 GPa range

Abstract

We present a simple method for determining equations of state (densities) of liquids up to ~10 GPa based on a precise measurement of the volume of the gasket hole in a diamond anvil cell. Key ingredients are the use of a highly sensitive optical pressure gauge, in our case SrClF:Sm 2+ and ruby, the preparation of gaskets which maintain a well-defined geometry of the sample chamber, and the application of corrections due to elasticity of the diamonds. We show that, following a certain procedure, the method allows under favorable conditions measurements of the equations of state with a precision of 1-3%. Result on the equation of state of the 4:1 methanol-ethanol mixture as well as of Daphne fluids 7474 and 7676 are presented. Measurements on water to 5.5 GPa allow a direct evaluation of the precision of the method.

Keywords

High pressure, diamond anvil cell, fluids, equation of state, [PHYS] Physics [physics]

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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