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Eastern-European Journal of Enterprise Technologies
Article . 2015 . Peer-reviewed
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Optimum conditions determination of methyl methacrylate obtaining over tungsten-containing catalyst

Authors: Dmytruk, Yuliia; Ivasiv, Volodymyr; Nebesnyi, Roman; Maykova, Svitlana;

Optimum conditions determination of methyl methacrylate obtaining over tungsten-containing catalyst

Abstract

The main common methods of methyl methacrylate producing are acetoncyanohydrin method and oxidation of isobutylene and tert-butanol. Because of the significant drawbacks of these methods, it is important to develop new, alternative ways of methyl methacrylate obtaining, one of which could be aldol condensation of methyl propionate with formaldehyde in the gas phase. The actual task for today is to find out effective catalysts for this process. For this aim, methyl propionate condensation with formaldehyde was studied in the presence of B 2 O 3 -P 2 O 5 -WO 3 /SiO 2 catalyst, which previously has showed high activity in the condensation of propionic acid with formaldehyde to methacrylic acid. The paper also investigates the influence of methanol on the side reaction of methyl propionate hydrolysis; it was found that adding methanol causes a slight increase in MMA selectivity, but the yield of unsaturated products decreases, and therefore adding methanol to the reaction mixture for the MP condensation with FA over B 2 O 3 -P 2 O 5 -WO 3 /SiO 2 catalyst is impractical. The optimum conditions for MP condensation with FA, namely temperature 653 K and contact time 12 s were found. Under these conditions, in the presence of B 2 O 3 -P 2 O 5 -WO 3 /SiO 2 catalyst with an atomic ratio of components B:P:W 3:1:0.6 respectively total yield of MMA and MAA was 31.91% while their total selectivity was 32.3%.

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Keywords

УДК 541.128.13, метилметакрилат; метакрилова кислота; метилпропіонат; формальдегід; каталізатор; гетерогенний каталіз; альдольна конденсація, methyl methacrylate; methacrylic acid; methyl propionate; formaldehyde; catalyst; heterogeneous catalysis; aldol condensation, метилметакрилат; метакриловая кислота; метилпропионат; формальдегид; катализатор; гетерогенный катализ; альдольная конденсация

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    3
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Average
Average
Average
gold