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Synthesis and structure of aroxy-tetra-p-tolylantimony (4-MeC6H4)4SbOC6H2Br2-2,6-(t-Bu)-4

Синтез и строение ароксида тетра-пара-толилсурьмы (4-MeC6H4)4SbOC6H2Br2-2,6-(t-Bu)-4
Authors: ANDREEV P.V.; SHARUTIN V.V.; SHARUTINA O.K.;

Synthesis and structure of aroxy-tetra-p-tolylantimony (4-MeC6H4)4SbOC6H2Br2-2,6-(t-Bu)-4

Abstract

Penta- p -tolylantimony interaction with 2,6-dibromo(4- tert -butyl)phenol has led to synthesis of the complex tetra- p -tolylantimony 2,6-dibromo(4- tert -butyl)phenoxide, whose structure has been established by X-ray diffraction. The antimony atom in the molecule (4-MeC 6 H 4 ) 4 SbOC 6 H 2 Br 2 -2,6-( t -Bu)-4 has distorted trigonal-bipyramidal coordination with the aroxy group in axial position. The bond Sb-O is 2.229(2) A, the axial angle CSbO is 176.82(10)°

Keywords

рентгеноструктурный анализ, synthesis, molecular structure, tetra-p-tolylantimony 2,6-dibromo(4-tert-butyl)phenoxide, TETRA-P-TOLYLANTIMONY,2,6-DIBROMO(4-TERT-BUTYL)PHENOXIDE,SYNTHESIS,MOLECULAR STRUCTURE,X-RAY ANALYSIS,6-ДИБРОМ(4-ТРЕТ-БУТИЛ)ФЕНОКСИД ТЕТРА-ПАРА-ТОЛИЛСУРЬМЫ,СИНТЕЗ,МОЛЕКУЛЯРНАЯ СТРУКТУРА,РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ, УДК 547.563.4, 2,6-дибром(4-трет-бутил)феноксид тетра-пара-толилсурьмы, УДК 546.865, синтез, УДК 548.312.5, молекулярная структура, УДК 547.53.024, X-ray analysis

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
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