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Other literature type . 2023
License: CC BY
Full-Text: http://www.mdpi.com/2673-6918/3/1/17/pdf
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Article . 2023 . Peer-reviewed
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Abraham Solvation Parameter Model: Revised Predictive Expressions for Solute Transfer into Polydimethylsiloxane Based on Much Larger and Chemically Diverse Datasets

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 20 Feb 2023 English Publisher:MDPI AGJournal:Compounds, volume 3, pages 205-223 (eissn: 2673-6918, Copyright policy )
Authors: Amy Zhou; Laine Longacre; Ramya Motati; William E. Acree;

doi: 10.3390/compounds3010017

Abraham Solvation Parameter Model: Revised Predictive Expressions for Solute Transfer into Polydimethylsiloxane Based on Much Larger and Chemically Diverse Datasets

Abstract

Updated Abraham model correlations are reported for the transfer of organic solutes and inorganic gases to a polydimethylsiloxane coating from both water and the gas phase based on published experimental data for more than 220 different compounds. The derived mathematical expressions back-calculate the observed partitioning behavior to within standard deviations of the residuals of 0.206 and 0.176 log units, respectively.

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Keywords

Physics, QC1-999, Physical and theoretical chemistry, QD450-801, gas-to-organic coating partition coefficients, linear free energy relationships, water-to-organic coating partition coefficients, polydimethylsulfoxide

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Top 10%
Average
Average
gold