The paper presents a study of structurization processes in the wood-cement systemmixed with the buffer solutions and the improvement of service properties of products produced therefrom. Infrared spectroscopy, X-ray phase analysis, and pH measurements show that structurization processes in wood-cement systems depend on the acidity of aqueous solution, the behavior of hydration, neutralization, and polycondensation reactions with the formation of polymer products including those with cement grout components and functional groups of wood. It is shown that phosphate buffer solutions used for mixing wood-cement compositions improve their strength properties and reduce water absorption. The optimum acidity of the buffered medium for service properties of the wood-cement systemis pH = 4.8.