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Eastern-European Journal of Enterprise Technologies
Article . 2018 . Peer-reviewed
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Investigation of the electrochromic properties of Ni(OH)2 films on glass with ITO­Ni bilayer coating

Authors: Kotok, Valerii; Kovalenko, Vadym;

Investigation of the electrochromic properties of Ni(OH)2 films on glass with ITO­Ni bilayer coating

Abstract

Electrochromic films have been deposited onto glass coated with indium-tin oxide (ITO) and glass with ITO and a thin layer of metallic nickel deposited onto it. Nickel was deposited onto the surface of the ITO coating from nickel electroplating solution. The metallic nickel was deposited onto the surface of ITO at the following parameters – cathodic current density 0.5 A/dn 2 , deposition time 3 s. Such deposition parameters were chosen, because at longer deposition time and (or) higher current density, the deposited layer of metallic nickel became opaque. The two substrates were then used in the deposition of Ni(OH) 2 electrochromic films using the cathodic template synthesis method. As a result, it was revealed that the electrochromic film deposited onto glass with ITO-Ni coating possesses higher specific characteristics than that deposited on bare ITO-coated glass: higher coloration degree and higher oxidation-reduction currents on the cyclic voltamperogram. However, it was also revealed that the film possessing better characteristics, on the contrary, has lower reversibility of the coloration-bleaching process. Based on the obtained data, the mechanism that explains the role of the intermediate metal layer was proposed. The mechanism is that the deposited layer of metallic nickel forms additional contacts between the substrate surface and the electrochromic film. The nickel layer can also assist in securing the electrochromic film, and during film deposition has a positive effect on current distribution. On the other hand, the lower reversibility of the coloration-bleaching process of the film on ITO-Ni coating can be explained by gradual oxidation of metallic nickel in the basic medium. At the same time, it was revealed that deposition of metallic nickel leads to some decrease of the substrate transparency.

Keywords

электрохромизм; электроосаждение; тонкие пленки; Ni(OH)2; никель; индий-оловянный оксид; гидроксид никеля, electrochromism; electrodeposition; thin films; Ni(OH)2; nickel; indium-tin oxide; nickel hydroxide, UDC 544.653.1, електрохромізм; електроосадження; тонкі плівки; Ni(OH)2; нікель; індій-олов'яний оксид; гідроксид нікелю

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
gold