The most suitable sites for solar photovoltaic power installations are determined through a comprehensive assessment of the meteorological, economic and environmental criteria of the energy potential areas. The basic criteria for location selection are evaluated using an analytical hierarchy process method based on multi-criteria decision-making technique for large-scale solar photovoltaic projects. The analytical hierarchy process model is also applied to evaluate areas of high solar potential and factors that are primary criteria for determinate the site suitability index modelling. This method considers various conditions, such as production and technological considerations, which aim to maximise the short-term profit from the project and the efficiency of power generation. In the study, a consistency ratio of suitable localities was determined and proper alternatives for the construction of photovoltaic installations were evaluated. In addition to local meteorology and related satellite measurement data, the country’s radiation values also were compared by converting a digital elevation model data using the tool «Area solar radiation» in GIS. As a result of calculating the site suitability index with the ArcGIS weighted overlay tool, it was concluded that 1.17 % (1016.8 km2) of the country are the most suitable sites for the installation of solar PV systems. These areas mainly include Khizi, Gobustan, Hajigabul, Beylagan, Sharur, Babek and Jeyranchol zones. The total number of locations identified accross the country, classified into 3 categories according to their level of suitability, includes 40 sites. Eight of these high suitability sites, all in Nakhchivan Autonomous Republic, contain 11 % (109.2 km2) of the total potential area. The remaining 32 sites, corresponding to areas with medium and low energy potential, cover 28 % (284.6 km2) and 61 % (623 km2), respectively. When these areas are completely covered with PV panels, it will be possible to fully supply the energy demand of the country with solar energy.