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Study of Cobalt Nanoparticle Modified Gold Electrode

Authors: Fanani, N.; Murwani, I.K.; Kurniawan, F.;

Study of Cobalt Nanoparticle Modified Gold Electrode

Abstract

Було проведено виявлення фосфатів за допомогою золотого електрода, модифікованого наночастинками кобальту. Наночастинки оксиду кобальту отримували змішуванням розчину хлориду кобальту з 10 % гліцерином і додаванням розчину гідроксиду амонію при перемішуванні протягом 2 годин при 50 °C. Потім розчин залишали на 12 годин. Отриманий осад відфільтрували і відпалили при 700°C протягом години. Отримані наночастинки кобальту змішали з нафіоном, потім прикріпили до золотого дроту для формування модифікованого електрода з наночастинок кобальту. Ефективність цього електрода перевіряли у порівнянні з розчином фосфату за допомогою триелектродної системи Autolab Metrohm типу AUT 84948. Вимірювання проводили шляхом занурення модифікованого кобальтового золотого електрода, підключеного до триелектродної системи Metrohm Autolab. Усі вимірювання фосфатів проводили в буферних розчинах KHP і KCl. Вольт-амперограмми KHP не показали піків анодного та катодного струмів, але у фосфатному розчині (10 ppm NaH2PO4) показали піки катодних струмів при потенціалі – 1,009 В. Це вказувало на чутливість електрода до розчинів фосфатних іонів. Катодний струм зростає зі збільшенням концентрації фосфату. Межа виявлення вимірювання становить 0,47 ppm. Phosphate detection using Cobalt nanoparticle modified gold electrode has been carried out. Cobalt oxide nanoparticles were produced by mixing a solution of cobalt chloride with 10 % glycerol and adding Ammonium hydroxide solution with stirring for 2 hours at 50 °C using a magnetic stirrer. The solution was then allowed to stand for 12 hours. The precipitate obtained was filtered and calcined at 700 °C for one hour. The obtained cobalt nanoparticles are mixed with nafion, then attached to a gold wire to form a modified cobalt nanoparticle electrode. The performance of this electrode was tested against a phosphate solution using a three-electrode system of the Autolab Metrohm type AUT 84948. Measurements were made by immersing a modified cobalt gold electrode connected to the Metrohm Autolab three-electrode system. All phosphate measurements were carried out in KHP and KCl buffer solutions. Voltammograms of KHP did not show peaks of anodic and cathodic currents but in phosphate solution (10 ppm NaH2PO4) showed peaks of cathodic currents at a potential of – 1.009 V. This indicated that the electrode was sensitive to phosphate ion solutions. The cathodic current increases with the phosphate concentration. The measurement detection limit is 0.47 ppm.

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Keywords

кобальтовий електрод, phosphates, cobalt electrode, циклічна вольт-амперометрія, potentiometry, sensor, фосфати, сенсор, потенціометрія, cyclic voltammetry

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
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