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Unlocking New Frontiers: Photo‐Isomerism and Magnetic Properties in Multifunctional Hetero‐Tetra‐Metallic Complexes

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 25 Feb 2025Embargo end date: 10 Apr 2025 France English Publisher:WileyJournal:Chemistry – A European Journal, volume 31 (issn: 0947-6539, eissn: 1521-3765, Copyright policy )Funded by:DFG | unidentified, ANR | SMAC
Authors: Ingrid Suzana; Jérémy Forté; Sébastien Pillet; El‐Eulmi Bendeif; Moritz Malischewski; Valérie Marvaud;

doi: 10.1002/chem.202402601 , 10.17169/refubium-46990

pmid: 39964217

pmc: PMC11979684

Unlocking New Frontiers: Photo‐Isomerism and Magnetic Properties in Multifunctional Hetero‐Tetra‐Metallic Complexes

Abstract

AbstractHetero‐tetra‐metallic complexes, FeNOCuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo‐isomerism, were obtained through the rational assembly of the photo‐switching nitroprusside anion FeNO with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the FeNOCuTbCo complex which is one of the few examples of a photo‐isomerisable SMM.

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Keywords

High-Spin molecules, Chemie und zugeordnete Wissenschaften, [CHIM] Chemical Sciences, Hetero-poly-metallic, Multifunctionality, Photo-isomerism, Single-molecule magnet, Research Article

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
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Average
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