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synthesis and structure of tri(meta-tolyl)antimony bis(benzenesulfonate)

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jan 2015Publisher:FSAEIHE South Ural State University (National Research University)Journal:«Bulletin of the South Ural State University series "Chemistry"», volume 15, pages 93-97 (issn: 2076-0493, eissn: 2412-0413, Copyright policy )
Authors: SHARUTIN V.V.; SHARUTINA O.K.; SENCHURIN V.S.;

doi: 10.14529/chem150414

synthesis and structure of tri(meta-tolyl)antimony bis(benzenesulfonate)

Abstract

Tri(meta-tolyl)antimony bis(benzenesulfonate) m-Tol3Sb(OSO2C6H5)2 (1) has been synthesized by interaction of tri(meta-tolyl)antimony with benzenesulfonic acid in the presence of tert-butyl hydroperoxide (mole ratio 1:2:1) in ether solution. Antimony atoms in 1 have trigonal-bipyramidal coordination with arenesulfonate substituents in axial positions (OSbO 171.05(11), CSbC 116.21(19), 117.38(18), 126.40(15)). The SbC and SbO distances equal 2.091(4), 2.098(4), 2.115(4) и 2.105(2), 2.116(3) Å. Intermolecular contact (Sb···O 3.421(3) Å) occurs between the central atom and the oxygen atom of sulfonate group. Взаимодействием три(мета-толил)сурьмы с бензолсульфоновой кислотой в присутствии третбутилгидропероксида (1:2:1 мольн.) в растворе эфира синтезирован бис(бензолсульфонат) три(мета-толил)сурьмы (m-Tol3Sb(OSO2C6H5)2 (1). Атомы сурьмы в 1 имеют тригонально-бипирамидальную координацию с аренсульфонатными заместителями в аксиальных положениях (OSbO 171,05(11), CSbC 116,21(19), 117,38(18), 126,40(15)). Расстояния SbC и SbO равны 2,091(4), 2,098(4), 2,115(4) и 2,105(2), 2,116(3) Å. Между центральным атомом и атомом кислорода сульфонатной группы имеет место внутримолекулярный контакт (Sb···O 3.421(3) Å). V.V. Sharutin, vvsharutin@rambler.ru O.K. Sharutina, sharutinao@mail.ru V.S. Senchurin, senvl@rambler.ru South Ural State University, Chelyabinsk, Russian Federation Шарутин Владимир Викторович – доктор химических наук, профессор, старший научный сотрудник УНИД, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail: vvsharutin@rambler.ru Шарутина Ольга Константиновна – доктор химических наук, профессор, кафедра аналитической химии, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail: sharutinao@mail.ru Сенчурин Владислав Станиславович – кандидат химических наук, кафедра органической химии, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail: senvl@rambler.ru

Related Organizations
Keywords

третбутилгидропероксид, рентгеноструктурный анализ, benzenesulfonic acid, tri(meta-tolyl)antimony, ГРНТИ 31.21, tert-butyl hydroperoxide, molecular structure, TRI(META-TOLYL)ANTIMONY,BENZENESULFONIC ACID,TERT-BUTYL HYDROPEROXIDE,MOLECULAR STRUCTURE,X-RAY DIFFRACTION ANALYSIS,ТРИ(МЕТА-ТОЛИЛ)СУРЬМА,БЕНЗОЛСУЛЬФОНОВАЯ КИСЛОТА,ТРЕТБУТИЛГИДРОПЕРОКСИД,МОЛЕКУЛЯРНАЯ СТРУКТУРА,РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ, бензолсульфоновая кислота, X-ray diffraction analysis, УДК 548.312.5, три(мета-толил)сурьма, молекулярная структура, УДК 547.53.024

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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