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Fractal Structure of Nanoporous Carbon Obtained by Hydrothermal Carbonization of Plant Raw Materials

Authors: Mandzyuk, V.I.; Lisovskiy, R.P.;

Fractal Structure of Nanoporous Carbon Obtained by Hydrothermal Carbonization of Plant Raw Materials

Abstract

Методом низькотемпературної порометрії досліджено фрактальну структуру пористих вуглецевих матеріалів, отриманих гідротермальною карбонізацією рослинної сировини в діапазоні температур 600 ÷ 1100 °С. Встановлено, що за температур карбонізації 600 ÷ 800 °С формуються матеріали з розвиненою мікропористою структурою, поверхнева фрактальна розмірність яких становить 2,58. За вищих температур карбонізації значення фрактальної розмірності поверхні зменшується до значення 2,17, що свідчить про формування майже гладкої поверхні за рахунок інтенсивного видалення атомів карбону з приповерхневих шарів частинок матеріалу, зменшення кількості мікропор з їх переходом у мезопори, об’єднання дрібних вуглецевих кластерів в більш крупніші та формування мікрочастинок непористого вуглецевого матеріалу. The fractal structure of porous carbon materials (PCMs) obtained by hydrothermal carbonization of plant raw materials in the temperature range of 600 ÷ 1100 °С is investigated using the low-temperature porometry method. It is set that materials with a developed microporous structure and a surface fractal dimension of 2.58 are formed at carbonization temperatures of 600 ÷ 800 °C. At higher carbonization temperatures, the value of the fractal dimension of the surface decreases to 2.17, which indicates the formation of an almost smooth surface due to the intensive removal of carbon atoms from the surface layers of the material particles, a decrease in the number of micropores with their transition to mesopores, the combination of small carbon clusters in larger and the formation of microparticles of non-porous carbon material.

Keywords

низькотемпературна порометрія, питома поверхня, specific surface, пористий вуглець, porous carbon, low-temperature porometry, фрактальна структура, fractal structure

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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