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Materials Research Bulletin
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New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 2020 Russian Federation English Publisher:Elsevier BVJournal:Materials Research Bulletin, volume 126, page 110,850 (issn: 0025-5408, Copyright policy )
Authors: Kokh, A. E.; Kononova, N. G.; Shevchenko, V. S.; Uralbekov, B.; Ezhov, Dmitry M.; Svetlichnyi, Valerii A.; Goreiavcheva, A.; +2 Authors

doi: 10.1016/j.materresbull.2020.110850

New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties

Abstract

Abstract Herein we report the growth of new RxLayScz(BO3)4 (x + y+z = 4, R = Sm, Tb) crystals with large second-harmonic generation (SHG) responses. The obtained compounds, grown from eutectic LiBO2-LiF flux by the TSSG method, crystallize in the space group P321 with the cell parameters a = 9.800(15) A and c = 7.9565(7) A for Sm0.34La0.68Sc2.98(BO3)4 and a = 9.7976(7) A and c = 7.9567(12) A for Tb0.23La0.77Sc3(BO3)4. These crystalline materials also exhibit luminescent properties related to the optical transitions of Tb3+ and Sm3+; specifically, Tb0.23La0.77Sc3(BO3)4 shows a strong green emission that is dominated by the 5D4 to 7F5 transition. The studied crystals’ SHG intensities were higher than those of KDP crystals, revealing their potential uses in various nonlinear optics applications.

Country
Russian Federation
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Keywords

оптические свойства, бораты скандия, хантит, редкоземельные бораты

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
17
Top 10%
Top 10%
Top 10%
Green