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Journal of Statistical Physics
Article . 2005 . Peer-reviewed
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https://dx.doi.org/10.48550/ar...
Article . 2003
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Infinite Compressibility States in the Hierarchical Reference Theory of Fluids. I. Analytical Considerations

Infinite compressibility states in the hierarchical reference theory of fluids. I: Analytical considerations
Authors: Reiner, Albert;

Infinite Compressibility States in the Hierarchical Reference Theory of Fluids. I. Analytical Considerations

Abstract

In its customary formulation for one-component fluids, the Hierarchical Reference Theory yields a quasilinear partial differential equation for an auxiliary quantity f that can be solved even arbitrarily close to the critical point, reproduces non-trivial scaling laws at the critical singularity, and directly locates the binodal without the need for a Maxwell construction. In the present contribution we present a systematic exploration of the possible types of behavior of the PDE for thermodynamic states of diverging isothermal compressibility kappa[T] as the renormalization group theoretical momentum cutoff approaches zero. By purely analytical means we identify three classes of asymptotic solutions compatible with infinite kappa[T], characterized by uniform or slowly varying bounds on the curvature of f, by monotonicity of the build-up of diverging kappa[T], and by stiffness of the PDE in part of its domain, respectively. These scenarios are analzyed and discussed with respect to their numerical properties. A seeming contradiction between two of these alternatives and an asymptotic solution derived earlier [Parola et al., Phys. Rev. E 48, 3321 (1993)] is easily resolved.

J. Stat. Phys., in press. Minor changes to match the published version

Keywords

numerical analysis, Statistical Mechanics (cond-mat.stat-mech), finite differences, Foundations of fluid mechanics, FOS: Physical sciences, nonlinear partial differential equations, stiffness, Stochastic methods applied to problems in equilibrium statistical mechanics, Statistical mechanics of liquids, Condensed Matter - Statistical Mechanics, liquid-vapor transitions

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average
Green
bronze