
Our world faces an urgent need for a greener industry with reduced water consumption and zero pollution, alleviating water scarcity problems. Membrane distillation (MD) is being explored for production of clean water from industrial waste streams in the steel, textile, food and other industries. Several challenges need to be overcome to achieve a full commercial market breakthrough for MD: Membrane wetting, scaling, and fouling. We plan to accept the challenges by using superhydrophobic membranes. Such membranes are also useful in oil-water separation, and a range of environmental applications. During the FET “HARMONIC” project, two RORs Max Planck-MPIP and NCSR-Demokritos developed complementary technologies for membrane superhydrophobicity, which impart extreme antiwetting, antiscaling and antifouling membranes. The technologies are based on plasma activation or plasma nanotexturing (NCSRD) followed by wet nanofilament growth (MPIP) or plasma deposition (NCSRD) for hydrophobization. Both institutions will advance their technology readiness level so the technology is validated - demonstrated in relevant environment (TRL 5-6), and will design, build, and test small scale pilot equipment for fabricating rolls of superhydrophobic membranes in a roll-to-roll format. For the upscaling of the technology NCSRD and MPIP, will cooperate with two industrial partners, namely Europlasma and SolSep respectively companies with large experience with roll-to-roll plasma or wet processes respectively. Moreover, they will team up with Aquastill, a manufacturer of commercial MD modules for industrial wastewater treatment. A market search and a business plan will be elaborated, for creating a spin-off company commercializing the superhydrophobic membranes, and processes. The range of applications will go well beyond MD.
MEloDIZER implements high-performance membranes and modules in strategic applications of membrane distillation (MD), hence providing the decisive step for the success of MD. These core components are fabricated with a focus on feasible wide uptake and on sustainability, substituting harmful materials and protocols with >80% of benign solvents and relying on green chemistry principles. Both flat-sheets and innovative hollow-fibres are produced, striking the optimum between productivity and energy efficiency, as well as minimising fouling/wetting phenomena, also by applying novel sacrificial coatings while membranes are in situ. Optimised modules are developed with a focus on hydrodynamics and energy recovery improvements. These activities are strongly supported by sustained modelling tasks, conducted at different scales to (i) control the relationship between membrane properties and performance, (ii) customise module geometry, and (iii) increase system efficiency and automation. The membranes and modules are thus rationally installed as core components of four MD prototypes spanning three orders of magnitude of productivity. Two prototypes (2-5 m3/day, 0.5-2 m3/day) are demonstrated in industrial facilities (textile, beverage, chemical industries) to reuse wastewater (70-90%), thus reducing water footprint and approaching zero waste, as well as to recovery valuable nutrients as secondary raw materials from aquaculture wastewater. Two prototypes (50-100 L/day, 10-20 L/day) are demonstrated as low-cost, ready-to-use, passive, autonomous, decentralised units, delivering drinking water from saline and challenging sources at community and family level. All prototypes are run with 90-100% sustainable energy from waste heat and/or solar energy, with careful designs that maximise membrane and system performance. Quantitative, robust evaluations of market entry and environmental benefits act as input data for each innovation activity in MEloDIZER and to promote exploitation.